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1 Department of Geological Sciences, University of Missouri–Columbia, Columbia, Missouri 65211
In the Black Hills, South Dakota, anatectic migmatites that formed above the second sillimanite isograd comprise mesosomes dominated by quartz, biotite, sillimanite, plagioclase, and sporadic poikiloblasts of K-feldspar, melanosomes dominated by biotite and sillimanite, and leucosomes. Some leucosomes have near-minimum granite composition, but many lack alkali elements and have fibrolitic sillimanite instead of feldspar. The proportion of Si/Al is the same in both leucosome types. The sillimanite-containing leucosomes include fluorapatite, which indicates high activity of F. The lack of alkali feldspar in these leucosomes is attributed to its instability relative to sillimanite + quartz in the presence of fluids with high aH+/aK+ ratios that evolved from the crystallizing leucosomes. It is suggested that quartz-aluminosilicate segregations and veins in other high-grade terranes may also represent pegmatitic melts in which alkali feldspar crystallization was inhibited by high activities of hydrogen, resulting in loss of alkali elements.
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