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1 Geology Department, University of Illinois at Urbana-Champaign, 245 Natural History Building, MC-102, Urbana, Illinois 61801, USA
2 Environmental Science and Waste Technology Division, MS J514, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA
3 Idaho National Engineering and Environmental Laboratory, P.O. Box 1625, Idaho Falls, Idaho 83415, USA
4 Water Resources Division, MS 420, U.S. Geological Survey, 345 Middlefield Road, Menlo Park, California 94025, USA
5 Berkeley Center for Isotope Geochemistry, Department of Geology and Geophysics, University of California, Berkeley, California 94720, USA
6 Earth Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA
7 Water Resources Division, U.S. Geological Survey, 8505 Research Way, Middleton, Wisconsin 53562, USA
8 U.S. Geological Survey, 900 North Skyline Drive, Idaho Falls, Idaho 83402, USA
9 Chemical Science and Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA
Preferential flow paths are expected in many groundwater systems and must be located because they can greatly affect contaminant transport. The fundamental characteristics of radiogenic isotope ratios in chemically evolving waters make them highly effective as preferential flow path indicators. These ratios tend to be more easily interpreted than solute-concentration data because their response to water-rock interaction is less complex. We demonstrate this approach with groundwater 87Sr/86Sr ratios in the Snake River Plain aquifer within and near the Idaho National Engineering and Environmental Laboratory. These data reveal slow-flow zones as lower 87Sr/86Sr areas created by prolonged interaction with the host basalts and a relatively fast flowing zone as a high 87Sr/86Sr area.
Key Words: groundwater tracers isotope ratios Snake River Plain aquifer properties aqueous solutions
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