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Sr isotope tracing of aquifer interactions in an area of accelerating coal-bed methane production, Powder River Basin, Wyoming

¹ Department of Geology and Geophysics, University of Wyoming, Laramie, Wyoming 82071, USA
² Wyoming Department of Environmental Quality, 122 West 25th Street, Cheyenne, Wyoming 82001, USA
³ U.S. Bureau of Land Management, 5353 Yellowstone Road, Cheyenne, Wyoming 82003, USA
⁴ Wyoming State Geological Survey, Laramie, Wyoming 82071, USA

Sr isotope data on groundwater samples from coal and overlying sandstone aquifers in the eastern Powder River Basin, Wyoming, demonstrate that the Sr isotope ratio effectively identifies groundwater from different aquifers where major ion geochemistry and O and H stable isotope data fail. Groundwaters from sandstone aquifers have a uniform ⁸⁷Sr/⁸⁶Sr ratio of 0.7126–0.7127. Waters from coal seams vary from ⁸⁷Sr/⁸⁶Sr ratio = 0.7127 near the recharge area to 0.7151 farther into the basin. The distinct Sr isotope signatures of sandstone and coal aquifers may reflect different sources of Sr in these two rock types: Sr in sandstones is held primarily in carbonate cement, whereas coals contain more radiogenic Sr in organic matter. The Sr isotope ratio is useful in identifying wells that contain mixed waters, whether due to well construction or to incomplete aquifer isolation. Measurement and continued monitoring of the Sr isotope ratio in groundwaters should provide a powerful tool for characterizing the impact of the burgeoning coal-bed methane industry on the hydrology of the Powder River Basin.

Key Words: coal • coal-bed methane • isotopes • groundwater • Wyoming

This article has been cited by other articles:

				E. L. Brinck, E. L. Brinck, J. I. Drever, and C. D. Frost The geochemical evolution of water coproduced with coalbed natural gas in the Powder River Basin, Wyoming Environmental Geosciences, December 1, 2008; 15(4): 153 - 171. [Abstract] [Full Text] [PDF]

				C. E. Campbell, B. N. Pearson, and C. D. Frost Strontium isotopes as indicators of aquifer communication in an area of coal-bed natural gas production, Powder River Basin, Wyoming and Montana Rocky Mountain Geology, November 1, 2008; 43(2): 171 - 197. [Abstract] [Full Text] [PDF]