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Isotopic composition of gypsum in the Macquarie Island ophiolite: Implications for the sulfur cycle and the subsurface biosphere in oceanic crust

¹ Department of Geological Sciences, 2534 C.C. Little Building, University of Michigan, Ann Arbor, Michigan 48109-1063, USA
² Department of Earth Sciences, and Centre for Ore Deposit Research, University of Tasmania, GPO Box 252-79, Hobart 7001, Australia
³ Southampton Oceanography Centre, School of Ocean and Earth Science, University of Southampton, Southampton SO14 3ZH, UK
⁴ Division of Earth and Ocean Sciences, Box 90230, 103 Old Chemistry Building, Duke University, Durham, North Carolina 27708-0230, USA

The O, S, and Sr isotope compositions were determined for 17 samples of gypsum that replaced anhydrite in the sheeted-dike complex of the Macquarie Island ophiolite. Elevated ³⁴S (26.2–29.0) and ¹⁸O values (12.5–14.4) of gypsum compared to those of seawater sulfate are the result of microbial sulfate reduction. Low organic carbon contents and little sulfate reduction in sediments, plus a large basaltic Sr component in the gypsum (⁸⁷Sr/⁸⁶Sr = 0.70446–0.70524), indicate that the sulfate source was not pore waters in the overlying sediment. Low ³⁴S values of sulfide in basalt lavas are consistent with microbial reduction of seawater sulfate within the volcanic rocks. Tectonic activity at the slow-spreading ridge allowed evolved formation waters to enter hot sheeted-dike complex basement, resulting in heating and precipitation of anhydrite. Results show that microbes can leave geochemical tracers of their activity in oceanic basement and that anhydrite can be preserved in oceanic crust and may be of significance for the oceanic sulfur budget.

Key Words: sulfates • hydrothermal processes • bacteria • biosphere • mid-ocean ridges

This article has been cited by other articles:

				P. A. Rivizzigno and J. A. Karson Structural expression of oblique seafloor spreading in the Macquarie Island ophiolite, Southern Ocean Geology, February 1, 2004; 32(2): 125 - 128. [Abstract] [Full Text] [PDF]