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Crystal molds on Mars: Melting of a possible new mineral species to create Martian chaotic terrain

¹ Department of Geological Science and Geological Engineering, Queen's University, Kingston, Ontario K7L 3N6, Canada
² Department of Chemistry, Queen's University, Kingston, Ontario K7L 3N6, Canada

Images sent back by the Mars Exploration Rover Opportunity from the Meridiani Planum show sulfate-rich rocks containing plate-shaped voids with tapered edges that are interpreted as crystal molds formed after a late-stage evaporite mineral has been removed. Experimental studies of the MgSO₄-H₂O system at low temperatures reveal that the triclinic phase MgSO₄·11H₂O exhibits a crystal morphology that matches the shapes of these molds. MgSO₄·11H₂O melts incongruently above 2 °C to a mixture of 70% epsomite (MgSO₄·7H₂O) and 30% H₂O by volume. When this occurs while crystals are encased in sediment, plate-shaped voids remain. The existence of ice, low surface temperatures, and the high sulfate content of surface rocks and soil on Mars makes MgSO₄·11H₂O a possible mineral species near the surface at high latitudes or elsewhere in the subsurface. If an evaporite layer contained a significant amount of this phase, incongruent melting would result in a rapid release of a large volume of water and could explain some of the landform features on Mars that are interpreted as outflow channels. MgSO₄·11H₂O would not survive a sample return mission unless extraordinary precautions were taken.

Key Words: sulfate • epsomite • Mars • mineralogy • incongruent melting

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