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Figure 2. Plot of log oxygen fugacity versus pressure (both in MPa) illustrating an isothermal (1350 °C) section in the C-O system and how a graphite-bearing, low-f O2 basalt (IW buffer conditions; IW = iron + wustite) would intersect the graphite-gas surface with decreasing pressure in a magma ascent. The pressure at which a CO-rich gas first forms is dependent on the intrinsic f O2, aFeO, and temperature of the basalt (Fogel and Rutherford, 1995). Assuming the basalt carries <2000 ppm C, the oxidation would be complete in a small pressure range beginning at 40 MPa (Nicholis and Rutherford, 2005).
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